Kinetics of epoxidation of aliphatic alkenes by dimethyldioxirane: Steric effects

Authors
Michelena-Baez, E Navarro-Eisenstein, AM Banks, HD Vasquez, PC Baumstark, AL
Citation
E. Michelena-baez et al., Kinetics of epoxidation of aliphatic alkenes by dimethyldioxirane: Steric effects, HETEROCYC C, 6(2), 2000, pp. 119-122
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLIC COMMUNICATIONS
ISSN journal
07930283 → ACNP
Volume
6
Issue
2
Year of publication
2000
Pages
119 - 122
Database
ISI
SICI code
0793-0283(2000)6:2<119:KOEOAA>2.0.ZU;2-L
Abstract
Kinetic data for epoxidation of three series of aliphatic alkenes by dimeth yldioxirane in dried acetone showed the reaction to be sensitive to steric effects; consistent with the current spiro transition state model.