An Atlantic meridional transect of surface water dimethyl sulfide concentrations with 10-15 km horizontal resolution and close examination of ocean circulation
S. Belviso et al., An Atlantic meridional transect of surface water dimethyl sulfide concentrations with 10-15 km horizontal resolution and close examination of ocean circulation, J GEO RES-A, 105(D11), 2000, pp. 14423-14431
Underway measurements of dimethyl sulfide (DMS) in the Atlantic surface wat
ers have been made during the ALBATROSS campaign from 65 degrees N to 45 de
grees S along about 30 degrees W. The main patterns of DMS variability in s
ubtropical waters of both hemispheres were the existence of (1) a poleward
negative gradient of DMS (0.04 nM/degrees latitude) paralleling the tempera
ture and salinity meridional trends and opposite to that of chlorophyll a (
chl a) and particulate DMSP (pDMSP), and (2) sharp DMS enhancements, up to
twenty fold the background levels, coinciding almost systematically with th
ermohaline frontal zones. We observed that DMS concentrations and TOPEX/Pos
eidon sea level anomalies (SLAs) were clearly in opposition of phase in the
subtropical and tropical waters of the Atlantic. Neither meridional change
s in pDMSP nor in chi a concentrations account for these large-scale (15 de
grees-20 degrees latitude) DMS variations. It is suggested that the spatial
distribution of DMS is highly sensitive to the upper ocean dynamics. The t
ropical Atlantic is a zone of contrasted DMS levels with two broad maxima a
ssociated (1) with the cyclonic circulations generated by the North Equator
ial currents and (2) with the South Equatorial Current, a situation very mu
ch resembling the autumnal meridional distribution of surface pCO(2). A clo
se examination of the South Atlantic subtropical front (38 degrees-43 degre
es S) show that DMS and in situ validated satellite chi a have a distinct s
patial distribution suggesting important spatial segregation of biogeochemi
cal processes in the frontal zones. These observations at different spatial
scales provide indications for the existence of a DMS-climate link through
frontogenesis and surface ocean circulation in the Atlantic.