Permanent densification behavior and Si-29 MAS NMR of SiO2-K2O-CaO-SrO glasses

In permanent densification of xSiO(2). 0.4(100 - x)K2O . 0.4(100 - x)CaO . 0.2(100 - x)SrO glasses (x = 41.2-66.7) in mol% by the 3 and 6 GPa high-pre ssure treatments a peculiar behavior was found in the glasses of x below 50 mol%. The skeleton structures composed of SiO4 units in the glasses were i nvestigated on the undensified and densified glasses by means of Si-29 magi c angle spinning (MAS) NMR spectroscopy. From the peak deconvolution of MAS NMR spectra the Q(n) fractions of SiO4 structural-units, where n (n = 0-4) means the number of bridging oxygen, were examined. At first, the skeleton structures in the undensified glasses are clarified. Then the skeleton str uctures of the densified glasses are discussed in comparison with those of the undensified glasses, Irrespective of the x value, the fractions of Q(n) of small n-values increased with an increase in the applied pressure, indi cating that some of the Si-O-Si bonds are broken under the applied pressure and the skeleton structures were kept even after a release of the applied pressure. It is concluded that other causes should be considered as the ori gin of the present peculiar behavior, (C) 2000 Elsevier Science B.V. All ri ghts reserved.