Crystal nucleation and growth in glasses from inorganic wastes from urban incineration

This paper reports the results of a study of the feasibility of recycling t he fly ashes from domiciliary waste incineration by producing glasses and g lass-ceramics. The major components of the fly ashes, Tyseley (F + L) and T yseley (F), which were from a British domiciliary incinerator, were CaO, Si O2 and Al2O3 but nucleating agents, such as TiO2 P2O5 and Fe2O3, were also present in reasonable amounts. Tyseley (F + L) was similar to a waste (Tirm e F + L) studied previously by the authors and hence glass and glass-cerami c development concentrated on Tyseley (F). It was found that a glass (desig nated TYS100) of suitable viscosity could be obtained from the waste withou t the need for any additives. The properties of this glass were similar to those of other glasses made from incinerator waste. The heat treatment requ ired to crystallise the TYS100 glass was nucleation at 560 degrees C for 55 min followed by crystal growth at 1050 degrees C for 15 min. The main crys talline phase in the resulting glass-ceramic was akermanite (Ca2MgSi2O7) wi th some TiO and TiSi2 forming in the later stages of heat treatment. The ak ermanite existed in a thin surface layer and also as spherulites in the bul k; the TiO and TiSi2 crystals were associated with the spherulites. The mec hanical properties and erosion resistance were superior to the glass and ac ceptable for applications such as tiles for the building industry and those requiring erosion resistance. (C) 2000 Elsevier Science B.V. All rights re served.