Direct electrochemical synthesis of organotin and lead compounds with pyridine-2-thione ligand

Authors
Kumar, S Kishore, D Mehta, RK
Citation
S. Kumar et al., Direct electrochemical synthesis of organotin and lead compounds with pyridine-2-thione ligand, J INDIAN CH, 77(5), 2000, pp. 254-255
Citations number
11
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
ISSN journal
00194522 → ACNP
Volume
77
Issue
5
Year of publication
2000
Pages
254 - 255
Database
ISI
SICI code
0019-4522(200005)77:5<254:DESOOA>2.0.ZU;2-S
Abstract
The electrochemical oxidation of anodic metals Sn and Pb in binary system c onsisting of acetonitrile (MeCN) and dimethylformamide (DMF) as solvent and pyridine-2-thione (pyt-H) as solute, gives complexes [Sn(pyt)(2)] and [Pb( pyt)(2)], respectively. Pyridine-2-thione (pyt-H) acts as a bidentate ligan d and that the geometry of the complexes is tetrahedral.