Liquid crystalline polyfluorenes for blue polarized electroluminescence

A series of 9,9-dialkyl-poly(fluorene-2,7-diyl)s containing linear and bran ched alkyl substituents with a M-n of up to 200000 g/mol has been synthesiz ed. Moreover, some of the polymers were end capped with a suitable hole tra nsport functionality, such as a triphenylamine derivative, to improve their charge transport properties and to control the molecular weight. The therm al alignment of these novel polymers on a rubbed polyimide layer led to hig hly anisotropic film formation with dichroic ratios (absorption parallel an d perpendicular to the rubbing direction) of up to 26 in absorption and 21 in emission.