By measuring the ratio of p- to s-polarized light intensities reflected at
an angle of incidence of 45 degrees from a transparent solid, the refractiv
e index of that solid can be determined. The critical factors affecting the
accuracy of the refractive index measurement using this technique are disc
ussed. The extension of this technique to materials which are weakly absorb
ing, or that have non-ideal surfaces, is also discussed and the errors that
arise from the neglect of these effects are quantified.