Mechanism of bipolar diffusion of intercalated ions in layered crystals

Authors
Dugaev, VK
Citation
Vk. Dugaev, Mechanism of bipolar diffusion of intercalated ions in layered crystals, PHYS ST S-B, 219(1), 2000, pp. 31-37
Citations number
19
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICA STATUS SOLIDI B-BASIC RESEARCH
ISSN journal
03701972 → ACNP
Volume
219
Issue
1
Year of publication
2000
Pages
31 - 37
Database
ISI
SICI code
0370-1972(200005)219:1<31:MOBDOI>2.0.ZU;2-K
Abstract
The diffusion of intercalated ions in layered crystals is considered. We ca lculate the corrections to the diffusion coefficient due to the Coulomb int eraction between ions and electrons. The model predicts the linear dependen ce of the diffusion coefficient on the concentration of intercalated ions N o The effective diffusion coefficient depends on distance which indicates a deviation from classical diffusion behavior.