The single-nucleon knockout reactions Be-9(B-14, B-13 + gamma)X and Au-197(
B-14, B-13 + gamma)X, at an incident energy of 60 MeV per nucleon, have be
en used to probe the structure of B-14 and of the core fragment B-13. A dom
inant 2s configuration is deduced for the neutron in the ground state of B-
14. The longitudinal momentum distribution for this state is consistent wit
h "neutron halo" structure. Spin assignments for B-13 excited states at 3.4
8 and 3.68 MeV are proposed based on the observed spectroscopic factors for
one-neutron removal.