Reactivity of Mo(PMe3)(5)H-2 towards catecholborane: synthesis and structure of Mo(PMe3)(4)(eta(2)-H(2)BCat)H

Authors
Hascall, T Bridgewater, BM Parkin, G
Citation
T. Hascall et al., Reactivity of Mo(PMe3)(5)H-2 towards catecholborane: synthesis and structure of Mo(PMe3)(4)(eta(2)-H(2)BCat)H, POLYHEDRON, 19(9), 2000, pp. 1063-1066
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
19
Issue
9
Year of publication
2000
Pages
1063 - 1066
Database
ISI
SICI code
0277-5387(20000515)19:9<1063:ROMTCS>2.0.ZU;2-W
Abstract
Mo(PMe3)(5)H-2 reacts with catecholborane (CatBH) to give Mo (PMe3)(4)(eta( 2)-H(2)BCat)H. Structural characterization by X-ray diffraction suggests th at the complex is best represented as a borohydride complex, as opposed to a boryl-hydride derivative Mo(PMe3)(4)(BCat)H-3. (C) 2000 Elsevier Science Ltd All rights reserved.