Stability of polymerizing liquid flow in porous media

Citation
Cn. Satyadev et al., Stability of polymerizing liquid flow in porous media, POLYM REACT, 8(2), 2000, pp. 167-197
Citations number
14
Categorie Soggetti
Chemical Engineering
Journal title
POLYMER REACTION ENGINEERING
ISSN journal
10543414 → ACNP
Volume
8
Issue
2
Year of publication
2000
Pages
167 - 197
Database
ISI
SICI code
1054-3414(2000)8:2<167:SOPLFI>2.0.ZU;2-E
Abstract
This paper examines the flow stability of a polymerizing liquid in an aniso tropic porous medium. The polymerization reaction leads to an increasing vi scosity along the flow direction, particularly behind the advancing resin/a ir front, and may cause the miscible displacement process to become unstabl e and uneven. A linearized stability analysis of the flow within the filled region behind the liquid /air interface has been conducted. This reveals t hat under a moderate adverse viscosity gradient, the polymerization reactio n has the potential for stabilizing the flow process by damping out disturb ances of wavelengths above a critical size. Guidelines are provided for adj usting the composition of the reacting liquid and the anisotropic medium pe rmeability to stabilize the flow process.