Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex

Authors
Mao, BW Zhao, AG Huang, MY Jiang, YY
Citation
Bw. Mao et al., Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex, POLYM ADV T, 11(5), 2000, pp. 250-253
Citations number
5
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMERS FOR ADVANCED TECHNOLOGIES
ISSN journal
10427147 → ACNP
Volume
11
Issue
5
Year of publication
2000
Pages
250 - 253
Database
ISI
SICI code
1042-7147(200005)11:5<250:AHOSAC>2.0.ZU;2-E
Abstract
A new chiral polymer-metal complex, methylsulfosodium carboxymethyl-cellulo se-Pt complex (MS-NaCMC-Pt), has been prepared by the reaction of sodium ca rboxymethylcellulose with methylsulfonyl chloride and H2PtCl6. 6H(2), which was found to he able to catalyze the asymmetric hydrogenation of salicyl a lcohol to give (1S,2S)-2-(hydroxymethyl)-cyclohexanol at 28 degrees C and u nder 1 atm H-2, in > 90% product and optical yields, respectively. The cata lyst could be reused many times without any remarkable changes in optical c atalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd.