Pyrolysis for the simultaneous generation of oils and gases can be convenie
nt to obtain hydrocarbons and even to recover crude petrochemicals or to ge
nerate energy from waste plastics. A Gray-King apparatus has been used to p
yrolyze waste polyethylene (PE), polystyrene (PS), both separately and with
different compositions. Thermogravimetric analysis of waste plastics indic
ated the critical temperatures, which should be effective for pyrolysis. Th
e chosen heating rate was low in order to achieve higher liquid yields. The
results showed that waste PS yielded higher liquid, and waste PE yielded h
igher gaseous products. The dominant liquid product of PS waste was styrene
whereas for waste PE, prophenylbenzene was the dominant pyrolysis product.
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