Electroconduction of rubidium pyrophosphate modified by divalent cations

Authors
Marks, EA Burmakin, EI Antonov, BD Shekhtman, GS
Citation
Ea. Marks et al., Electroconduction of rubidium pyrophosphate modified by divalent cations, RUSS J ELEC, 36(5), 2000, pp. 516-521
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
36
Issue
5
Year of publication
2000
Pages
516 - 521
Database
ISI
SICI code
1023-1935(200005)36:5<516:EORPMB>2.0.ZU;2-T
Abstract
Solid solutions based on rubidium pyrophosphate are synthesized in the Rb4- 2xMxP2O7 systems (M = Ca, Sr, Ba, Ph). The temperature and concentration de pendences of their rubidium-cation conductivity are investigated. The X-ray data for the low- and high-temperature forms of Rb4P2O7 and also for solid solutions based on it are reported. The effect exerted by modifying cation M2+ on electrical properties of synthesized solid solutions is considered.