The crystal structure of Na3Bi5(PO4)(6) was solved using the single-crystal
X-ray diffraction technique. The structural refinement has led to a reliab
ility factor of R-1 = 0.0257 (wR(2) = 0.0533) for 428 independent reflectio
ns. This compound was found to crystallize in the cubic system (space group
I (4) over bar 3d) with eulytite structure and the lattice parameters: a =
10.097 (4) Angstrom, V = 1029.38 Angstrom(3), Z = 2, D-calc. = 5.43 g cm(-
3) (D-exp. = 5.32(5) g cm(-3)). The structure is characterized by the exist
ence of one single general position (48a) for oxygen anions and two disting
uished positions (16c)occupied by Na+ and Bi3+ cations, respectively. The s
ite occupation factors are equal to 3/8 and 5/8 for sodium and bismuth, res
pectively. Although all P-O distances are identical (1.529(4) Angstrom), th
e O-P-O angles ranging from 108.06 (15) to 112.32 (31)degrees, show that [P
O4](3-) are rather distorted. Both sodium and bismuth cations are located i
n octahedral sites with corresponding mean distances of Na-O and Bi-O equal
to 2.428 and 2.386 Angstrom, respectively. As expected from the close valu
es of the ionic radii of Na+ and Bi3+, these distances lie in the same rang
e. (C) 2000 Editions scientifiques et medicales Elsevier SAS. All rights re
served.