RUTHENIUM(II) AND RUTHENIUM(III) BIPYRIDINE COMPLEXES AND THEIR CATALYTIC-OXIDATION PROPERTIES FOR ORGANIC-COMPOUNDS

Authors
ELHENDAWY AM ALKUBAISI AH ALMADFA HA
Citation
Am. Elhendawy et al., RUTHENIUM(II) AND RUTHENIUM(III) BIPYRIDINE COMPLEXES AND THEIR CATALYTIC-OXIDATION PROPERTIES FOR ORGANIC-COMPOUNDS, Polyhedron, 16(17), 1997, pp. 3039-3045
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
17
Year of publication
1997
Pages
3039 - 3045
Database
ISI
SICI code
0277-5387(1997)16:17<3039:RARBCA>2.0.ZU;2-1
Abstract
The new complexes [Ru-II(bpy)(2)L](PF6) and [Ru-III(bpy)(2)Cl-2]X (bpy = 2,2'-bipyridine; HL = acetylacetone, trifluoroacetylacetone, hexafl uoroacetylacetone, dibenzolymethane or tropolone; X = IO4 and PF6) hav e been prepared and characterized by spectroscopic measurements and al so investigated by cyclic voltammetry. They effectively catalyze the o xidation of alcohols, 3,5-di-t-bulycatechol and alkane in the presence of t-butyl hydroperoxide or N-methylmorpholine-N-oxide as co-oxidants . (C) 1997 Elsevier Science Ltd.