Reversal of pi-facial diastereoselection in the hydride reduction of selenanones. Further application of the exterior frontier orbital extension model

Authors
Tomoda, S Zhang, J Kaneno, D Segi, M Zhou, AJ
Citation
S. Tomoda et al., Reversal of pi-facial diastereoselection in the hydride reduction of selenanones. Further application of the exterior frontier orbital extension model, TETRAHEDR L, 41(23), 2000, pp. 4597-4601
Citations number
22
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
23
Year of publication
2000
Pages
4597 - 4601
Database
ISI
SICI code
0040-4039(20000612)41:23<4597:ROPDIT>2.0.ZU;2-T
Abstract
Reversal of pi-facial diastereoselection in the hydride reduction of 2-phen yl-4-selenanone (1b) and 6-phenyl-3-selenanone (2b) has been rationalized b y the exterior frontier orbital! extension model (EFOE model). (C) 2000 Els evier Science Ltd. All rights reserved.