Studies towards the total synthesis of methyl isosartortuoate: enantioselective synthesis of a precursor of the macrocycle

Authors
Liao, XB Xu, XX
Citation
Xb. Liao et Xx. Xu, Studies towards the total synthesis of methyl isosartortuoate: enantioselective synthesis of a precursor of the macrocycle, TETRAHEDR L, 41(23), 2000, pp. 4641-4644
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
23
Year of publication
2000
Pages
4641 - 4644
Database
ISI
SICI code
0040-4039(20000612)41:23<4641:STTTSO>2.0.ZU;2-N
Abstract
A concise synthesis of a precursor of dienyl cembranoids starting from gera niol is reported. All of the four chiral centers in the dienyl unit were es tablished by Sharpless kinetic resolution, asymmetric epoxidation and dihyd roxylation. (C) 2000 Elsevier Science Ltd. All rights reserved.