Unexpected conversion of vinyl sulfoxides into carbonyl compounds by meansof iodotrimethylsilane

Authors
Aversa, MC Barattucci, A Bonaccorsi, P Bruno, G Giannetto, P Policicchio, M
Citation
Mc. Aversa et al., Unexpected conversion of vinyl sulfoxides into carbonyl compounds by meansof iodotrimethylsilane, TETRAHEDR L, 41(22), 2000, pp. 4441-4445
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
22
Year of publication
2000
Pages
4441 - 4445
Database
ISI
SICI code
0040-4039(20000608)41:22<4441:UCOVSI>2.0.ZU;2-3
Abstract
The unexpected and previously unknown TMSI-promoted conversion of cl,P-unsa turated sulfoxides into carbonyl compounds and disulfides is described. It occurs in good yields under mild conditions. The examples provided support the generality and efficiency of this procedure which acts as a good method for removing the sulfinyl group with the advantage of transforming-the vin yl sulfoxides into carbonyl compounds. (C) 2000 Elsevier Science Ltd. All r ights reserved.