A convenient route to enantiomerically pure, conjugated dienes from sugar allyltin derivatives

Citation
S. Jarosz et al., A convenient route to enantiomerically pure, conjugated dienes from sugar allyltin derivatives, TETRAHEDR-A, 11(9), 2000, pp. 1997-2006
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
11
Issue
9
Year of publication
2000
Pages
1997 - 2006
Database
ISI
SICI code
0957-4166(20000519)11:9<1997:ACRTEP>2.0.ZU;2-M
Abstract
The transformation of sugar allyltin derivatives into enantiomerically pure dienes (R*w-CH=CH-CH=CH2) is presented. The internal double bond with the trans-configuration is formed regardless of the configuration of the starti ng sugar allyltin, (C) 2000 Elsevier Science Ltd, All rights reserved.