Computational aspects of kinetic analysis. Part D: The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods

Authors
Citation
Ak. Burnham, Computational aspects of kinetic analysis. Part D: The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods, THERMOC ACT, 355(1-2), 2000, pp. 165-170
Citations number
1
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
355
Issue
1-2
Year of publication
2000
Pages
165 - 170
Database
ISI
SICI code
0040-6031(20000731)355:1-2<165:CAOKAP>2.0.ZU;2-L
Abstract
This paper is Part D of a discussion of the computational stage of solid-st ate reactions as applied to the data sets of the ICTAC Kinetic Analysis Pro ject. This Part critically evaluates the results from the various participa nts and finds that kinetic analysis programs used by Burnham, Roduit, and O pfermann give very similar results. Isoconversional methods give kinetic pa rameters that agree qualitatively with those from subsequent nonlinear regr ession to appropriate models. Single-heating-rate methods work poorly and s hould not be used or published. (C) 2000 Elsevier Science B.V. All rights r eserved.