Excess molar enthalpies of binary mixtures containing propylene carbonate plus some n-alkoxy- and n-alkoxyethoxy-ethanols at 288.15, 298.15, and 313.15 K

Citation
F. Comelli et al., Excess molar enthalpies of binary mixtures containing propylene carbonate plus some n-alkoxy- and n-alkoxyethoxy-ethanols at 288.15, 298.15, and 313.15 K, THERMOC ACT, 354(1-2), 2000, pp. 89-97
Citations number
25
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
354
Issue
1-2
Year of publication
2000
Pages
89 - 97
Database
ISI
SICI code
0040-6031(20000717)354:1-2<89:EMEOBM>2.0.ZU;2-7
Abstract
Excess molar enthalpies, H-m(E), of binary mixtures containing propylene ca rbonate + six n-alkoxyethanols have been determined using an LKB Row microc alorimeter at 288.15, 298.15, and 313.15 K and at atmospheric pressure. The alkoxyethanols were 2-methoxyethanol, 2-ethoxyethanol, 2-butoxyethanol, 2- (2-methoxyethoxy)ethanol, 2-(2-ethoxyethoxy)ethanol, and 2-(2-butoxyethoxy) ethanol. From the experimental data, deviations in H-m(E) have been determi ned and fitted to the Redlich-Kister polynomial to estimate the binary inte ractions parameters. (C) 2000 Elsevier Science B.V. All rights reserved.