Sm. Gao et al., Influence of water and oxygen in the media on the process of benzene-thermal synthesis of GaP nanocrystals, ACT CHIM S, 58(6), 2000, pp. 643-646
Nanometer GaP crystal was synthesized by using the benzene - thermal synthe
sis method with GaCl3 - ethyl ether, GaCl3 - benzene and P as the starting
materials. The influence of remaining H2O and oxygen on the results was inv
estigated. The stability of products was studied by comparing the strength
of respective chemical bonds. The results indicate that both H2O and oxygen
have obvious effects on the reaction process and may even change the direc
tion of reaction in some case.