On the trail of CrO2Cl2 in its reactions with organic compounds

Authors
Citation
C. Limberg, On the trail of CrO2Cl2 in its reactions with organic compounds, CHEM-EUR J, 6(12), 2000, pp. 2083-2089
Citations number
63
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY-A EUROPEAN JOURNAL
ISSN journal
09476539 → ACNP
Volume
6
Issue
12
Year of publication
2000
Pages
2083 - 2089
Database
ISI
SICI code
0947-6539(20000616)6:12<2083:OTTOCI>2.0.ZU;2-B
Abstract
The simple metal oxo compound chromyl chloride, CrO2Cl2, displays a very co mplex reactivity with respect to alkanes, olefins, alcohols, and epoxides. Synergetic investigations applying various techniques and methods have only recently led to an understanding of the key steps in the corresponding mec hanisms, which are representative for more complex systems. Product formati on seems to be largely determined by radical reactions initiated by this d( 0)-metal compound.