New low-index liquid refractive index standard: SRM 1922

Citation
Jr. Verkouteren et Sd. Leigh, New low-index liquid refractive index standard: SRM 1922, FRESEN J AN, 367(3), 2000, pp. 226-231
Citations number
21
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY
ISSN journal
09370633 → ACNP
Volume
367
Issue
3
Year of publication
2000
Pages
226 - 231
Database
ISI
SICI code
0937-0633(200006)367:3<226:NLLRIS>2.0.ZU;2-Z
Abstract
A new standard for the calibration of refractometers has been developed. St andard Reference Material (SRM) 1922 is a mineral oil with a refractive ind ex n(D) = 1.46945 at 20 degrees C, which is within the range of the Brix sc ale (% sucrose). The change in refractive index with temperature (dn/dT) ha s been characterized for the range 15 degrees C to 35 degrees C to allow fo r calibrations within that range of temperatures. The refractive indices we re measured at 5 wavelengths in the visible spectrum by using the method of minimum deviation with a +/- 2-3 x 10(-5) uncertainty at 20 degrees C. The values of n(D) and dn(D)/dT were determined by fits of a two-term Cauchy f unction to the values at the measured wavelengths with a +/- 6 x 10(-5) unc ertainty in n(D) at 20 degrees C.