The structural characterization of YbI2(DME)(3)

Authors
Hibbs, DE Jones, C Richards, AF
Citation
De. Hibbs et al., The structural characterization of YbI2(DME)(3), J CHEM CRYS, 29(10), 1999, pp. 1107-1110
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
10
Year of publication
1999
Pages
1107 - 1110
Database
ISI
SICI code
1074-1542(199910)29:10<1107:TSCOY>2.0.ZU;2-V
Abstract
The preparation and structural characterization of [YbI2(DME)(2)] are repor ted. The complex crystallizes in the triclinic space group P 1: a = 13.0094 (10), b = 14.504(3), c = 14.668 (3) Angstrom, alpha = 115.281(10) beta = 1 06.74(2), gamma = 105.97(2)degrees The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.