Crystal structure of the molecular inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene with acetone (1 : 3)

Authors
Lu, GY Liu, F Liu, YJ He, WJ Li, Q Zhu, LG
Citation
Gy. Lu et al., Crystal structure of the molecular inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene with acetone (1 : 3), J CHEM CRYS, 29(10), 1999, pp. 1121-1125
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
10
Year of publication
1999
Pages
1121 - 1125
Database
ISI
SICI code
1074-1542(199910)29:10<1121:CSOTMI>2.0.ZU;2-G
Abstract
Crystal structure of inclusion complex of 5, 17-di-t-butyl-26, 28-disubstit uted calix[4]arene 3 with acetone, [(C54H58N2O6 . CH3COCH3) . 2CH(3)COCH(3) ], was determined by X-ray crystallographic analysis. It possesses space gr oup C2/c, with a = 26.277(8), b = 12.967(5), c = 20.355(4) Angstrom, beta = 124.845(14)degrees, and D-calc = 1.173 mg/m(3) for Z = 4. Crystal data ind icate that action of one molecule of compound 3 upon three molecules of ace tone forms a clathrate intermolecular inclusion complex.