The dynamics of triplet excitons in naphthalene crystals are investigated u
sing single terrylene molecules as local probes. Triplet excitations in the
host matrix are generated by Xe-lamp illumination. The triplet excitations
induce shifts in the resonance frequencies of the individual probe molecul
es. These excitation-induced frequency shifts fluctuate and relax on a time
scale of seconds subsequent to the matrix excitation. For the description
of the frequency shifts two models are applied. One is based on localized e
xcitations and is similar to the sudden-jump model. The other is based on m
obile excitations that are harvested by an energy funnel of trap states in
the vicinity of the probe molecule. The analysis indicates that the frequen
cy fluctuations result from triplet excitations migrating within the funnel
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