On the crystalline-amorphous supermolecular structure of poly(4-methyl-1-pentene) films cast from solution: experimental evidences and theoretical remarks.
A. Danch et A. Gadomski, On the crystalline-amorphous supermolecular structure of poly(4-methyl-1-pentene) films cast from solution: experimental evidences and theoretical remarks., J MOL LIQ, 86(1-3), 2000, pp. 249-257
We regard the formation of crystalline-amorphous structure of polymeric fil
ms cast from solution. We pay a special attention to its formation on a lev
el of single quasicrystalline domain, and try to embark on the problem, whe
n a possibly large group of such domains has to be considered. In the forme
r, one is nearly enforced to make use of a modification of the stochastic d
iffusion-limited aggregation model, first introduced by Witten and Sander.
In the latter, certain diffusion-type (Potts-like) models, invented for pol
ycrystalline microstructure formation, could be adopted. When considering t
he problem on the first level mentioned, one may notice an apparent agreeme
nt between experiment and theory, whereas on the second level, some concept
ual similarity seems to be attractive. (C) 2000 Elsevier Science B.V. All r
ights reserved.