Studies of positive muons implanted into solid elemental boron illustrate t
he various mu SR techniques of muon spin rotation, relaxation and resonance
. The chemical behaviour of positive muons and protons being similar, the l
ocal magnetic dipole and electrical quadrupole interactions with the boron
nuclei determined by these measurements should characterize the crystallogr
aphic site and electronic structure of interstitial protons. Muon diffusion
through the boron lattice becomes significant only above 500 K, with an ac
tivation energy of 0.33(2) eV, as determined from motional narrowing of the
rotation spectrum and evolution of the zero-field relaxation function. The
strong spin-spin couplings in boron prove suitable for demonstrating vario
us techniques of radiofrequency and level-crossing resonance, and also a no
vel form of spin echo detected in null external field. Copyright (C) 2000 J
ohn Wiley & Sons, Ltd.