SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURES OF PENTAMETHYLCYCLOPENTADIENYL-RUTHENIUM(II) AND CYCLOPENTADIENYL-RUTHENIUM(II) DIPHENYLPHOSPHINE COMPLEXES

Authors
LUBIAN RT PAZSANDOVAL MA
Citation
Rt. Lubian et Ma. Pazsandoval, SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURES OF PENTAMETHYLCYCLOPENTADIENYL-RUTHENIUM(II) AND CYCLOPENTADIENYL-RUTHENIUM(II) DIPHENYLPHOSPHINE COMPLEXES, Journal of organometallic chemistry, 532(1-2), 1997, pp. 17-29
Citations number
46
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
532
Issue
1-2
Year of publication
1997
Pages
17 - 29
Database
ISI
SICI code
0022-328X(1997)532:1-2<17:SPACOP>2.0.ZU;2-7
Abstract
The synthesis, characterization and single-crystal structure determina tion of chiral compounds (eta(5)-C5R5)Ru(pHph(2))(pph(3))Cl (R = H 3, R = Me 4) and prochiral Cp Ru(PHPh2)(2)Cl (6) are described. Compoun d 6 has been available from reaction of PHPh2 and several starting mat erials. The X-ray structure comparison between 3, 4 and 6 allowed us t o compare the influence of the phosphine, Cp and Cp ligands in these half-sandwich compounds. In addition, a structural investigation was carried out on CpR(NBD)Cl(7).