Chiral C-2 and C-1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior

Authors
Chisholm, MH Iyer, SS Streib, WE
Citation
Mh. Chisholm et al., Chiral C-2 and C-1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior, NEW J CHEM, 24(6), 2000, pp. 393-398
Citations number
15
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
24
Issue
6
Year of publication
2000
Pages
393 - 398
Database
ISI
SICI code
1144-0546(200006)24:6<393:CCACS(>2.0.ZU;2-J
Abstract
The preparation, structures and solution behavior of {(cyclooctane-1,5-diyl )bis[(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazol-2-yl ]borato-kappa N-1,kappa N-1'}metal, where metal = K, 1, or Tl, 2, {(cyclooc tane-1,5-diyl)[(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-in dazol-2-yl][(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indaz ol-2-yl]borato-kappa N-1,kappa N-1'}potassium-tetrahydrofuran(1/3), 3 . 3TH F, and {(cyclooctane-1,5-diyl)bis[(4R,7R)-7-isopropyl-4-methyl-4,5,6,7-tetr ahydro-2H-indazol-2-yl]borato-kappa N-1,kappa N-1'}potassium-tetrahydrofura n(1/4), 4 . 4THF, are reported.