[PtCl3(C2H4)](-)[(S,S)-(PhMeCH)(2)NH2](+): A new and versatile ionic organometallic chiral derivatizing agent for the determination of the enantiomeric composition of chiral unsaturated compounds by Pt-195 NMR spectroscopy

Authors
Uccello-Barretta, G Bernardini, R Lazzaroni, R Salvadori, P
Citation
G. Uccello-barretta et al., [PtCl3(C2H4)](-)[(S,S)-(PhMeCH)(2)NH2](+): A new and versatile ionic organometallic chiral derivatizing agent for the determination of the enantiomeric composition of chiral unsaturated compounds by Pt-195 NMR spectroscopy, ORG LETT, 2(13), 2000, pp. 1795-1798
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
13
Year of publication
2000
Pages
1795 - 1798
Database
ISI
SICI code
1523-7060(20000629)2:13<1795:[ANAVI>2.0.ZU;2-8
Abstract
The ionic complex [PtCl3(C2H4)](-)[(S,S)-(PhMeCH)(2)NH2](+) containing a ch iral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturat ed compounds including simple olefins: the diastereoisomeric mixtures arisi ng from the exchange of ethylene by the unsaturated analytes are easily det ected by Pt-195 NMR spectroscopy.