Syntheses and x-ray structures of novel main group bis(dialkylamino)phosphinimides

Authors
Schulz, S Raab, M Nieger, M Niecke, E
Citation
S. Schulz et al., Syntheses and x-ray structures of novel main group bis(dialkylamino)phosphinimides, ORGANOMETAL, 19(13), 2000, pp. 2616-2620
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
13
Year of publication
2000
Pages
2616 - 2620
Database
ISI
SICI code
0276-7333(20000626)19:13<2616:SAXSON>2.0.ZU;2-F
Abstract
Reactions of aminobis(dicyclohexylamino)phosphane with several aluminum tri alkyls R3Al (R = Me, Et, t-Bu) yield the simple Lewis acid-base adducts (Cy 2N)(2)P(H)N(H)AIR(3) (R = Me, 1; Et, 2; t-Bu, 3). Dimeric phosphiniminoalan es [(Cy2N)(2)P(H)NAIR(2)](2) (R = Me, 4; Et, 5) were obtained by reactions of aminobis(dicyclohexylamino)phosphane with the corresponding dialkyl alum inum hydride R2AlH. X-ray structure analyses were obtained from 1, 3, 4, an d 5.