We have exploited angle-resolved one-photon photoemission, two-photon photo
emission, and spot-profile analysis of low-energy electron diffraction to m
onitor the influence of surface morphology on the occupied and empty surfac
e states observed at Gamma on Cu(111). Surface morphology changes were indu
ced by homoepitaxial growth of Cu on Cu(111). A simple model of electron lo
calization on terraces successfully explains energy shifts and linewidth br
oadening of both surface states. Obviously, surface states may be used as s
ensitive probes of terrace-width distributions and other structural propert
ies.