Raman study of kinetics of graphitization of carbon blacks

Citation
Tw. Zerda et T. Gruber, Raman study of kinetics of graphitization of carbon blacks, RUBBER CHEM, 73(2), 2000, pp. 284-292
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
RUBBER CHEMISTRY AND TECHNOLOGY
ISSN journal
00359475 → ACNP
Volume
73
Issue
2
Year of publication
2000
Pages
284 - 292
Database
ISI
SICI code
0035-9475(200005/06)73:2<284:RSOKOG>2.0.ZU;2-T
Abstract
Raman spectra of laser heated carbon blacks provide information on the dyna mics of the graphitization process. Continuous wave and pulsed-laser heatin g is used. It is shown that two ordering mechanisms of distinctly different reaction rates are present during the heat treatment. The dominating mecha nism, during the initial stages of graphitization, is characterized by a ve ry fast rate. The rate during the later stages of the process, after the in itial first couple of seconds, is orders of magnitude slower.