Synthesis and structure of K3Ag2Zr4F23 and K3Ag2Hf4F23

Authors
Koller, D Muller, BG
Citation
D. Koller et Bg. Muller, Synthesis and structure of K3Ag2Zr4F23 and K3Ag2Hf4F23, Z ANORG A C, 626(6), 2000, pp. 1429-1433
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
6
Year of publication
2000
Pages
1429 - 1433
Database
ISI
SICI code
0044-2313(200006)626:6<1429:SASOKA>2.0.ZU;2-K
Abstract
Blue single crystals of K3Ag2Zr4F23 have been obtainend by heating up a mix ture of KCL, Ag-powder and ZrOCl2 . 8H(2)O under with Ar diluted F-2 (T = 5 50 degrees C, t similar to 70 d). The compound crystallizes monoclinic, spa ce group P2(1)/c-C-2h(5) (No.14) with a = 783,8(1)pm, b = 1117,4(2)pm, c = 1015,6(1)pm, beta = 97,45(1)degrees, Z = 2. The isotypic compound K3Ag2Hf4F 23, with a = 782,1(2) pm, b = 1115,4(2) pm, c = 1013,1(2) pm, beta = 97,51( 2)degrees, was prepared only as powder.