Chemical transport of solid solutions: Transport phenomena in the Co3O4/CoGa2O4 system

Authors
Patzke, GR Koepke, J Binnewies, M
Citation
Gr. Patzke et al., Chemical transport of solid solutions: Transport phenomena in the Co3O4/CoGa2O4 system, Z ANORG A C, 626(6), 2000, pp. 1482-1487
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
6
Year of publication
2000
Pages
1482 - 1487
Database
ISI
SICI code
0044-2313(200006)626:6<1482:CTOSST>2.0.ZU;2-6
Abstract
Chemical transport reactions are a suitable pathway to the preparation of m ixed spinels Co(Ga, Co)(2)O-4 in the CO3O4/COGa2O4 system. Solid solutions with specific Co-III/Ga-III ratios are accessible via variation of the sour er material compositions, because Co3O4 and CoGa2O4 are completely miscible . Electron microprobe analyses indicate the beginning of a zoning process i n the crystals deposited. Experiments are consistent with thermodynamic cal culations.