Wh. Paar et al., Suredaite, PbSnS3, a new mineral species, from the Pirquitas Ag-Sn deposit, NW-Argentina: mineralogy and crystal structure, AM MINERAL, 85(7-8), 2000, pp. 1066-1075
Suredaite, ideally PbSnS3, is a new mineral species from the Pirquitas Ag-S
n deposit (Province Jujuy, NW-Argentina). It was observed in symmetrically
banded veins in the Oploca district, and is associated with sphalerite, ars
enopyrite, pyrite-marcasite, cassiterite, cylindrite, franckeite, hocartite
, rhodostannite, and various Ag-Sb and Ag-Bi sulfosalts in minor amounts. S
uredaite occurs in layers up to 1 cm in thickness as aggregates of radially
arranged tabular-prismatic (single) crystals, has a metallic lustre, and a
dark grey streak. VHN50 ranges between 18.2 and 20.6 (mean 19.6) GPa, the
Mohs hardness is 2.5-3. It has perfect cleavages parallel to {001}, {101},
and {100}. The measured density varies between 5.54 and 5.88 g/cm(3), D-x w
as determined to be 5.615 g/cm(3). In reflected plane-polarised light, it i
s white and is not perceptibly bireflectant or pleochroic. It lacks interna
l reflections and is weakly anisotropic with metallic blue, mauve to brown
rotation tints. Specular reflectance percentages in air and in oil are tabu
lated from 400 to 700 nm and compared graphically with those for the type s
pecimen of teallite, PbSnS2. Electron microprobe analyses showed suredaite
to be chemically inhomogeneous with respect to the compositional variations
(in wt%): Pb 42.3-48.5, Ag 0.3-1.1, Fe 0.3-1.0, As 0.2-2.1, Sn 27.7-30.2,
S 23.1-24.7. The crystal structure determined from single-crystal X-ray dif
fraction data revealed orthorhombic symmetry [space group Pnma, Z = 4, a =
8.8221(3), b = 3.7728(3), c = 14.0076(3) Angstrom; V = 466.73(4) Angstrom(3
)]. The atomic arrangement is isostructural to the NH4CdCl3 structure type
which exists in a series of isotypic sulfides and selenide compounds. The s
uredaite structure, which is the natural analogue of synthetic PbSnS2, cons
ists of columns of double-edge sharing octahedra running parallel to the b
axis, which house the Sn atoms. These columns are linked by rods of eightfo
ld-coordinated Pb atoms. On the basis of the structure determination, the e
mpirically determined idealized formula follows a ([8])(Pb, As,Ag, Sn) ([6]
)(Sn,Fe)S-3 stoichiometry. Crystalchemical arguments suggest Ag possibly to
occupy interstitial sites according to the alternative formula ([4])(squar
e,Ag) ([8])(Pb, As, Sn) ([6])(Sn,Fe) S-3. The name of this new mineral spec
ies is in honor of R.J. Sureda Leston, head of the Department of Mineralogy
and Eco nomic Geology, University of Salta, Argentina.