Electron energy-loss spectrometry on lithiated graphite

Transmission electron energy-loss spectrometry was used to investigate the electronic states of metallic Li and LiC6, which is the Li-intercalated gra phite used in Li-ion batteries. The Li K edges of metallic Li and LiC6 were nearly identical, and the C K edges were only weakly affected by the prese nce of Li. These results suggest only a small charge transfer from Li to C in LiC6, contrary to prior results from surface spectra obtained by x-ray p hotoelectron spectroscopy. Effects of radiation damage and sample oxidation in the transmission electron microscopy are also reported. (C) 2000 Americ an Institute of Physics. [S0003-6951(00)04428-4].