Unusual alkali metal alpha- or beta-phenyl(trimethylsilyl)amides

Authors
Antolini, F Hitchcock, PB Lappert, MF Merle, P
Citation
F. Antolini et al., Unusual alkali metal alpha- or beta-phenyl(trimethylsilyl)amides, CHEM COMMUN, (14), 2000, pp. 1301-1302
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
2000
Pages
1301 - 1302
Database
ISI
SICI code
1359-7345(2000):14<1301:UAMAOB>2.0.ZU;2-B
Abstract
The synthesis (1-3 and 5) and structures (1-5) of the crystalline, hydrocar bon-soluble metal amides [M{mu-N(SiMe3)(SiMe2Ph)}(NCBut)(n)](2) [n = 0 and M = Li 1 (cis), M = Na 2 (trans) having intermolecular Na ... C contacts, o r n = 1 and M = Na (cis) 3], [Li{mu-N(SiMe3)Ph}-cis](2)[mu-{N(SiMe3)Ph}Li-c is](2) 4 and trans-[Na{mu-N(SiMe3)Ph}(tmen)] 5 are reported.