Solid state coordination chemistry of oxovanadium phosphates: hydrothermalsyntheses and structures of the network and chain phosphate phases [{Cu(bpy)}(2)(VO)(3)(PO4)(2)(HPO4)(2)]center dot 2H(2)O and [{Cu(terpy)}(2)(VO2)(3)(PO4)(HPO4)(2)]

Authors
Finn, R Zubieta, J
Citation
R. Finn et J. Zubieta, Solid state coordination chemistry of oxovanadium phosphates: hydrothermalsyntheses and structures of the network and chain phosphate phases [{Cu(bpy)}(2)(VO)(3)(PO4)(2)(HPO4)(2)]center dot 2H(2)O and [{Cu(terpy)}(2)(VO2)(3)(PO4)(HPO4)(2)], CHEM COMMUN, (14), 2000, pp. 1321-1322
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
2000
Pages
1321 - 1322
Database
ISI
SICI code
1359-7345(2000):14<1321:SSCCOO>2.0.ZU;2-T
Abstract
The hydrothermal reactions of Cu2O, the appropriate polypyridine ligand, Na 3VO4, H3PO4 and H2O at 200 degrees C yield the two-dimensional material [{C u(bpy)}(2)(VO)(3)- (PO4)(2)(HPO4)(2)]. 2H(2)O and the one-dimensional phosp hate [{Cu(terpy)}(2)(VO2)(3)(PO4)(HPO4)(2)], examples of the structure-dire cting role of secondary metal-ligand subunits on the architectures of vanad ium phosphates.