Enantioselective hydroboration of olefins catalysed by cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene

Authors
McCarthy, M Hooper, MW Guiry, PJ
Citation
M. Mccarthy et al., Enantioselective hydroboration of olefins catalysed by cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene, CHEM COMMUN, (14), 2000, pp. 1333-1334
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
2000
Pages
1333 - 1334
Database
ISI
SICI code
1359-7345(2000):14<1333:EHOOCB>2.0.ZU;2-0
Abstract
Cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino) naphthalene catalyse the hydroboration of indene, tetrahydronaphthalene and a range of styrenes in high yields, regioselectivities and with enantiomer excesses of up to 97%.