The dynamics of the unimolecular decomposition of the methanethiol radical
cation (CH3SH+) was investigated by direct classical trajectories in which
the interatomic forces were evaluated by semi-empirical AM1 calculations. A
t 170 kcal/mol, the methanethiol cation decomposition is found to be non-st
atistical. The abundances of product ions calculated for different initial
conditions are in reasonable agreement with those determined experimentally
. Our results corroborate that the coupling between the low- and high-frequ
ency vibrational modes is weak in the methanethiol cation. (C) 2000 Elsevie
r Science B.V. All rights reserved.