6-TRIFLUOROMETHANESULFONYLOXY-4(3H)-PYRIMIDINONES AS VERSATILE INTERMEDIATES FOR THE SYNTHESIS OF 6-FUNCTIONALIZED 4(3H)-PYRIMIDINONES

Citation
Ec. Taylor et al., 6-TRIFLUOROMETHANESULFONYLOXY-4(3H)-PYRIMIDINONES AS VERSATILE INTERMEDIATES FOR THE SYNTHESIS OF 6-FUNCTIONALIZED 4(3H)-PYRIMIDINONES, Tetrahedron letters, 38(25), 1997, pp. 4343-4346
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
25
Year of publication
1997
Pages
4343 - 4346
Database
ISI
SICI code
0040-4039(1997)38:25<4343:6AVI>2.0.ZU;2-8
Abstract
The reaction of 6-trifluoromethanesulfonyloxy-4(3H)-pyrimidinones with Me2Cu(CN)Li-2, and with vinyl tributyltin, trimethylsilylacetylene, a nd zinc cyanide with palladium catalysis, are described for the synthe sis of a variety of fully functionalized 6-substituted-4(3H)-pyrimidin ones of interest as herbicides.