PALLADIUM-CATALYZED SELECTIVE SYNTHESIS OF UNSYMMETRICAL BIARYLS FROMARYL HALIDES OR TRIFLATES AND ORGANOMANGANESE REAGENTS

Authors
RIGUET E ALAMI M CAHIEZ G
Citation
E. Riguet et al., PALLADIUM-CATALYZED SELECTIVE SYNTHESIS OF UNSYMMETRICAL BIARYLS FROMARYL HALIDES OR TRIFLATES AND ORGANOMANGANESE REAGENTS, Tetrahedron letters, 38(25), 1997, pp. 4397-4400
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
25
Year of publication
1997
Pages
4397 - 4400
Database
ISI
SICI code
0040-4039(1997)38:25<4397:PSSOUB>2.0.ZU;2-N
Abstract
Various functionalized unsymmetrical biaryls can be prepared in good t o excellent isolated yields by palladium-catalyzed coupling reaction o f aryl manganese chloride with aryl iodides, bromides or triflates. Th e reaction takes place rapidly and cleanly under mild conditions by us ing only 1% of palladium complexes. (C) 1997 Published by Elsevier Sci ence Ltd.