A NOVEL-APPROACH TO AN OXOBORANE AND ITS LEWIS BASE COMPLEX

Authors
ITO M TOKITOH N OKAZAKI R
Citation
M. Ito et al., A NOVEL-APPROACH TO AN OXOBORANE AND ITS LEWIS BASE COMPLEX, Tetrahedron letters, 38(25), 1997, pp. 4451-4454
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
25
Year of publication
1997
Pages
4451 - 4454
Database
ISI
SICI code
0040-4039(1997)38:25<4451:ANTAOA>2.0.ZU;2-9
Abstract
Reaction of dimethyl sulfoxide (DMSO) with 1,3,2,4-dithiastannaboretan e 3 bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsil yl)methyl]phenyl (Tbt), an the baron atom gave an oxoborane (Tbt-B=O; 4), which formed a complex with DMSO stable in solution. The formation of the complex was confirmed by B-11 NMR and a [3+2] cycloaddition re action with 2,4,6-tri-t-butylbenzonitrile oxide. (C) 1997 Elsevier Sci ence Ltd.