Capsules with beryllium ablators are very important targets for the DOE Nat
ional Ignition Facility (NIF) laser in the Inertial Confinement Fusion Prog
ram. Two leading candidates for fabricating beryllium capsules are the mach
ining and bonding of hemispheres, and physical vapor deposition of berylliu
m onto plastic or other shells. An attractive possibility would be to coat
a spherical mandrel with a thin layer of beryllium by a non-line-of-sight p
rocess. This coating could be applied via the chemical vapor deposition (CV
D) of beryllium.
Our first attempt at coating beryllium via CVD was done by using bis(cyclop
entadienyl)beryllium, (C2H5)(2)Be, as the precursor material. Results obtai
ned by use of (C5H5)(2)Be as the precursor material is discussed.
However, difficulties we encountered with use of the (C5H5)(2)Be precursor
material led us to examine a relatively unexplored area of beryllium chemis
try, namely that of its amines. This redirection also led us to change surr
ogate material for use in the developmental work.