(NH4)(15)[H3Mo57V6(NO)(6)O-189(H2O)(12)(VO)(6)]center dot similar to 60H(2)O: New nanocompound obtained by chemical embellishment of {M57V6}

Authors
Yang, WB Lin, X Lu, CZ Zhuang, HH Huang, JS
Citation
Wb. Yang et al., (NH4)(15)[H3Mo57V6(NO)(6)O-189(H2O)(12)(VO)(6)]center dot similar to 60H(2)O: New nanocompound obtained by chemical embellishment of {M57V6}, INORG CHEM, 39(13), 2000, pp. 2706
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
13
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000626)39:13<2706:(DST6>2.0.ZU;2-M
Abstract
By chemically embellishing metal-oxygen fragments into the three outer cavi ties of the nanoanion [H-3-Mo57V6(NO)(6)O-183(H2O)(18)](21-) ({Mo57V6}), a new nanostructural anion formulated as [H3Mo57V6(NO)(6)O-189- (H2O)(12)(VO) (6)](15-) ({Mo57V12}) was obtained. The embellishment leads to a new nanost ructural anion with some interesting results. Furthermore, the six embedded symmetry-related V2 centers have tetrahedral coordination environments and are verified as V-v ions via solid-state V-51 NMR spectrum.