Hydrotris(indazolyl)borate, Tp(4Bo) a surprisingly effective Tp ligand forsupramolecular assembly

Authors
Janiak, C Temizdemir, S Dechert, S
Citation
C. Janiak et al., Hydrotris(indazolyl)borate, Tp(4Bo) a surprisingly effective Tp ligand forsupramolecular assembly, INORG CH C, 3(6), 2000, pp. 271-275
Citations number
50
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
6
Year of publication
2000
Pages
271 - 275
Database
ISI
SICI code
1387-7003(200006)3:6<271:HTASET>2.0.ZU;2-3
Abstract
The assembly of T1Tp(4Bo) and M(Tp(4Bo))(2) (M e.g. Co, Ni) in the crystal is dictated by aromatic pi-pi and C-H ...pi interactions. This leads to the formation of chiral C-2-symmetrical pairs (for T1) or solvent-filled, abou t 30%-porous, non-covalent framework structures (for Co and Ni). The potass ium salt KTp(4Bo) features a kappa N,eta-C-C,eta(2)-C-N cation-pi coordinat ion mode - curious for a Tp-type ligand. (C) 2000 Elsevier Science S.A. All rights reserved.